Recently, POMs
lost three distinguished colleagues: Saul Wolfe, Richard Bader and A.J. Kresge.
Saul Wolfe, Dick Bader, Yvonne Chiang and Jerry Kresge |
1. Saul Wolfe
(1933-2011) was for many years an active participant in POMs, and he helped organize two meetings at
Queen’s University, in Kingston, where he spent much of his academic career before he was lured away to Simon
Fraser U.
Saul became involved with Phys. Org. Chem., working on his Ph.D. with Ray Lemieux, then at the University of Ottawa. Later on, through collaboration with Imre Czimadia (U of Toronto), he got into theoretical calculations, first semi-empirical and then ab initio. Some of his early studies were on the origins of the “Anomeric Effect” – a largely Canadian enterprise also known as the “Edward-Lemieux Effect”, after Jack Edward (another POMs participant and organizer) and Ray Lemieux.
Saul became involved with Phys. Org. Chem., working on his Ph.D. with Ray Lemieux, then at the University of Ottawa. Later on, through collaboration with Imre Czimadia (U of Toronto), he got into theoretical calculations, first semi-empirical and then ab initio. Some of his early studies were on the origins of the “Anomeric Effect” – a largely Canadian enterprise also known as the “Edward-Lemieux Effect”, after Jack Edward (another POMs participant and organizer) and Ray Lemieux.
Much of Saul’s other research was related to penicillin-type
derivatives, their synthesis and their mode of action as antibiotics. An obituary of Saul appeared in ACCN.
2. In January 2012, we lost another theoretical chemist, and
sometime POMs participant, Richard Bader (1931–2012). I first met Dick in 1963
when I was a graduate student at McMaster U. and where he had just joined the
faculty. Although I took no courses from him he was helpful to me when I was
preparing for exams in theoretical chemistry. Throughout the years I followed
the evolution of his ideas and was pleased to see him receive credit for them
late in his career. Dick is now
best known for his “Atoms in Molecules” (AIM) approach and the use of
stationary points in electron density to analyze chemical bonding, as expounded
in his published papers, reviews and books. See his website and links therein.
Younger folk may not know that Dick started out as a
physical organic chemist. His
Master’s research, with Art Bourns at McMaster, was a study of the mechanism of
the Chugaev reaction, using kinetic isotope effects, and his Ph.D. work with C. Gardner Swain (M.I.T.) was mainly on the origins and interpretation of solvent
isotope effects. It was as a
post-doc. with H.C. Longuet-Higgins (Cambridge, UK) that he got into the deeper, murkier waters of
theoretical chemistry.
There was very interesting article about Dick Bader in
Scientific Computing World (2003).
3. As reported earlier on the POMs main website, we also recently
lost A. Jerry Kresge (1926-2010).
Besides being one of the most eminent practitioners of physical organic
chemistry in North America, Jerry was also one of POMs' most stalwart members.
He died just two years after his wife and long-time collaborator, Yvonne Chiang. From the earliest years of POMs, in the 1970s, Jerry and Yvonne were active participants and frequent contributors.
Jerry Kresge and Yvonne Chiang |
A good synopsis of Jerry's career and his contributions to
physical organic chemistry can be read in a biographical essay written by John Richard and Rory More O'Ferrall, Advances of Physical Organic Chemistry, Volume
44, pages xiii - xxiii (2010).
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